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Development Progress of Novel Catalysts for Photocatalytic Degradation of Propylene Oxide Wastewater?

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Development of Novel Catalysts for Photocatalytic Degradation of Propylene Oxide Wastewater

with the acceleration of industrialization, propylene oxide, as an important chemical raw material, will produce a large amount of waste water containing toxic and harmful substances in the process of production and application. These wastewater, if not treated effectively, will pose a serious threat to the environment and human health. Photocatalytic technology, as a green and efficient environment-friendly technology, has been widely concerned in the field of propylene oxide wastewater treatment in recent years. This paper will focus on the theme of "development progress of new catalysts for photocatalytic degradation of propylene oxide wastewater", and introduce in detail the basic principles of photocatalytic technology, the development status of new catalysts and their application prospects in the treatment of propylene oxide wastewater.

1. PHOTOCATALYTIC TECHNOLOGY PRINCIPLES

Photocatalytic technology is a technology that uses light energy to drive chemical reactions, and its core is photocatalyst. Under the irradiation of visible light or ultraviolet light, the photocatalyst can convert light energy into chemical energy, thereby driving the degradation process of pollutants. In the treatment of propylene oxide wastewater, photocatalytic technology generates active oxygen species (such as hydroxyl radicals and superoxide anions) with strong oxidation by exciting the electronic transition of the photocatalyst. These active oxygen species can effectively degrade organic pollutants. Eventually, propylene oxide and its derivatives are converted into harmless small molecules, such as carbon dioxide and water.

2. traditional photocatalyst deficiency and improvement direction

Traditional photocatalysts, such as titanium dioxide (TiO₂) and zinc oxide (ZnO), have the advantages of high stability and low cost, but they have some limitations in practical applications. These catalysts have a narrow absorption range of light, mainly concentrated in the ultraviolet region, resulting in their low utilization in the visible region. The small specific surface area of traditional photocatalyst limits its loading capacity and reaction efficiency in wastewater. The agglomeration phenomenon of photocatalyst is also an urgent problem to be solved, and the agglomeration leads to the reduction of the surface area utilization of the catalyst, which in turn affects its catalytic performance.

In view of the above problems, researchers have carried out a lot of research on the development of new photocatalyst. Among them, modified metal oxides, composite semiconductor materials and noble metal supported photocatalysts have become hot research directions.

3. NEW TYPE CATALYST DEVELOPMENT AND CHARACTERISTICS

  1. modified metal oxide catalyst By surface modification or doping modification of metal oxides such as titanium dioxide and zinc oxide, the light absorption ability of the photocatalyst can be effectively improved. For example, by introducing nitrogen, carbon, fluorine and other elements to doping titanium dioxide, its light absorption range can be extended, so that it has a higher activity in the visible region. The modified metal oxide catalyst also has stronger redox ability, which can more effectively degrade the complex pollutants in propylene oxide wastewater.

  2. composite semiconductor material catalyst Composite semiconductor materials combine two or more semiconductor materials to complement each other and improve photocatalytic efficiency. For example, the composite of titanium dioxide and zinc oxide can form a catalyst with a larger specific surface area and more active sites, thereby improving its ability to treat propylene oxide wastewater. The compound semiconductor material can also reduce the recombination probability of electron-hole pairs by adjusting the electron transition path, and further improve the stability of the photocatalyst.

  3. noble metal supported photocatalyst Noble metal (such as platinum, gold, silver) supported photocatalyst has good application prospect in the treatment of propylene oxide wastewater because of its excellent electron transfer performance and stability. By loading the noble metal nanoparticles on the surface of the metal oxide or carbon-based material, the surface activity and catalytic efficiency of the photocatalyst can be significantly improved. For example, titanium dioxide photocatalyst supported by gold nanoparticles shows high photocatalytic activity under visible light, which can efficiently degrade propylene oxide and its derivatives.

Application of

4. Photocatalytic Technology in Propylene Oxide Wastewater Treatment

The composition of propylene oxide wastewater is complex and contains a variety of refractory organic pollutants. Photocatalytic technology has become an ideal choice for the treatment of this kind of wastewater because of its high efficiency and green characteristics. The development of new photocatalysts has further improved the treatment efficiency and stability of photocatalytic technology. For example, the modified titanium dioxide photocatalyst shows high catalytic activity in the treatment of propylene oxide wastewater, and can completely degrade pollutants into harmless substances in a relatively short time. The introduction of composite semiconductor materials and noble metal supported photocatalyst not only improves the activity of photocatalyst, but also expands its application range in wastewater treatment.

5. Future Development Direction and Challenges

Although the new photocatalyst has made significant progress in the treatment of propylene oxide wastewater, it still faces some challenges. For example, how to further improve the visible light utilization of photocatalyst, enhance its stability and selectivity, and reduce its cost, is the focus of future research. In the practical application of photocatalytic technology, there are still some problems such as slow reaction rate and high equipment investment, which need to be solved through technological innovation and process optimization.

"Progress in the development of new catalysts for photocatalytic degradation of propylene oxide wastewater" is a research field full of potential. With the continuous emergence of new catalysts and the further improvement of photocatalytic technology, it is believed that in the near future, photocatalytic technology will play a greater role in the treatment of propylene oxide wastewater, and provide a more green and efficient solution to solve environmental pollution problems.


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