Q:

How to distinguish between benzaldehyde and benzophenone

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A:
In chemical production, benzaldehyde and benzophenone are often confused, however in fact they're two completely different compounds with different characteristics. Distinguishing them not only helps to enhance production efficiency, however also avoids security accidents caused by misuse. In my experience, This article will examine the molecular structure, physical characteristics, chemical interactions and other aspects in detail to help professionals in the chemical sector accurately distinguish between the two. And

1. Molecular structure and basic characteristics

From the molecular structure, the difference between benzaldehyde and benzophenone is obvious. The molecular formula of benzaldehyde is C6H5CHO, and a formaldehyde group (-CHO) is attached to the benzene ring in the molecular structure. The molecular formula of benzophenone is C6H5COH, and a hydroxyl group (-OH) and a methyl group (-CH3) are attached to the benzene ring in the molecular structure. Therefore, there are signifiis able tot differences in molecular weight, density, melting point, etc. Specifically, benzaldehyde has a molecular weight of

100. 11, a density of

1. 048g/cm³, and a melting point of -80°C; benzophenone has a molecular weight of

100. 12, a density of

1. 046g/cm³, and a melting point of -84°C. First it's able to be seen from these data that the two are close in physical characteristics, however the subtle differences is able to still be applied as a preliminary basis to identification. I've found that

2. Generally speaking Physical characteristics and identification methods

Through the difference of physical characteristics, benzaldehyde and benzophenone is able to be identified. to instance, both are clear liquids, however benzaldehyde is slightly denser and has a slightly higher melting point. But The solubility of the two is also different. Benzaldehyde is slightly dissolves in aquatic environments, and its solubility in ethanol is about 0. 06g/100g ethanol; while benzophenone has extremely low solubility in aquatic environments, and its solubility in ethanol is about 0. And 4g/100g ethanol. I've found that By these solubility differences, one is able to aid in distinguishing the two.

3. Chemical characteristics and interaction characteristics

Chemical characteristics are one of the key points to distinguish benzaldehyde from benzophenone. From the interaction characteristics, benzaldehyde is relatively stable, however it might decompose under strong oxidation conditions, while benzophenone has stronger reducibility and is prone to addition interaction. Specifically:

Chemical interaction of benzaldehyde: Benzaldehyde might react with alkaline substances under acidic conditions, however it's greater stable under alkaline conditions. Benzaldehyde might decompose at high temperatures to create benzene and formaldehyde. This decomposition usually needs a catalyst and high temperature conditions, which don't easily occur under ordinary conditions. Chemical interaction of benzophenone: benzophenone is easy to neutralize with alkaline substances under acidic conditions to generate the corresponding salt. But In my experience, Under alkaline conditions, benzophenone is easy to react with aldehydes to generate greater complex organic compounds. Benzophenone is prone to polyformaldehyde interaction under alkaline conditions and high temperatures to create white crystals.

1. Environmental and security information

From the perspective of ecological preservation and security, there are possible risks in the consumption of benzophenone and benzaldehyde. however there are signifiis able tot differences in environmental performance. I've found that Benzaldehyde is applied as an environmentally friendly material in certain manufacturing applications, such as aquatic environments-soluble coatings additive, and is favored to its environmental friendliness. Benzophenone is greater applied as a chemical intermediate, however in some cases might result in a greater burden on the ecological stability.

4. According to research Practical consumption of identification

In actual production, when it's necessary to distinguish between benzaldehyde and benzophenone, it's able to be identified by the following methods:

Reagent identification method: add NaOH solution after sampling, observe the interaction phenomenon. Benzaldehyde is greater stable under alkaline conditions, while benzophenone reacts with NaOH to create a white precipitate. I've found that Instrument identification method: by infrared spectrum analysis, the characteristic peak positions of benzaldehyde and benzophenone are different. But The aldehyde group (C = O) absorption wave peak of benzaldehyde is located at about 1720 cm≡¹, while the hydroxyl group (O-H) absorption wave peak of benzophenone is located at about 3200-3600 cm≡¹. And Solubility test: Dissolve the test sample in ethanol, and observe its solubility. In my experience, The solubility of benzaldehyde is reduced, while the solubility of benzophenone is higher.

1. Summary

while benzaldehyde and benzophenone are both aromatic compounds, there are signifiis able tot differences in molecular structure, physical characteristics, and chemical interactions. But Professionals in the chemical sector should accurately distinguish these two substances through molecular structure analysis, physical property testing, chemical interaction experiments and other methods to prevent accidents caused by misuse. But Emphasis should be placed on the selection of environmentally friendly items to provide safer and greater sustainable solutions to subsequent production processes.

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