Difference between ethyl acetoacetate and butyl acetate
1. Definition and Sources
both ethyl acetoacetate and butyl acetate are esters, but their sources and structures are different.
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Definition of acetoethyl ester: acetoethyl ester is an esterification reaction product of acetic acid and ethanol under acidic conditions. Acetic acid (CH3COOH) and ethanol (C2H5OH) were esterified under the catalysis of sulfuric acid to produce ethyl acetate (CH3COOCH2CH3) and water. This compound is acidic because-OAc (methoxycarbonyl) in the ester group can dissociate the acidic proton.
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Definition of Butyl Acetate: Butyl acetate is the esterification product of acetic acid with butanol (C4H9OH) under acidic conditions. Acetic acid (CH3COOH) reacts with butanol (C4H9OH) catalyzed by sulfuric acid to give butyl acetate (CH3COOC4H9) and water. This compound also has the conjugated acidity of the ester, but the size of its alcohol group is larger, which affects its physical and chemical properties.
Comparison with the structure of the ester group
the ester group is the core structure of these two compounds, but the ester group of the two compounds is significantly different.
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Ester group of ethyl acetoacetate: The ester group of ethyl acetoacetate is methoxycarbonyl (AcO-), I .e.-OAc. The structure of this ester group makes it acidic, but due to the presence of methoxy groups, the acidity is relatively weakened. The ethyl acetoester has a smaller ester group and a lower molecular weight, making it chemically more stable.
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The ester group of butyl acetate: The ester group of butyl acetate is a butoxycarbonyl (O-C4H9) group, I .e.,-O-C4H9. The structure of this ester group gives it a larger molecular weight and a longer carbon chain, which affects its physical properties, such as solubility, melting point, etc. The ester group of butyl acetate is bulky, which may lead to some special behaviors in chemical reactions.
Chemical Properties and Applications of 4.
The chemical properties of ester compounds are closely related to their structures, and the performance of ethyl acetate and butyl acetate is also different.
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Chemical properties: due to the small ester group of ethyl acetate, its solubility in water is higher, and it has a certain acidity, which makes it show certain activity in some reactions. The ester group of butyl acetate is larger, which may lead to its low solubility in water, and its chemical properties are more stable, and it is not easy to occur esterification reaction.
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Application areas:
- ethyl acetoacetate commonly used in medicine, food industry as a preservative and stabilizer. Its small molecular structure makes it suitable as a pharmaceutical intermediate while having a long shelf life in food.
- butyl acetate: Commonly used in solvents or as a plastic inhibitor. Its larger molecular structure makes it more effective in some solvent applications, but may not be active enough in some reactions.
5. selection recommendations
in practical applications, the choice of ethyl acetate or butyl acetate needs to be determined according to specific requirements.
- If a more stable and chemically active ester compound is desired, ethyl acetoacetate may be considered.
- If a larger molecular structure is desired and has specific physical properties, butyl acetate may be considered.
Summary
although ethyl acetate and butyl acetate are both esters, their sources, structures, chemical properties and applications are different. Understanding the difference between the two can help to better select the appropriate compound for a particular industrial or chemical application.
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