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The difference between insoluble sulfur and sulfur

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In the chemical industry, the morphological changes of sulfur directly affect its application and performance. Among them, insoluble sulfur and sulfur are two common sulfur forms. Although they are similar in appearance, they are significantly different in chemical properties and uses. This article will analyze the difference between insoluble sulfur and sulfur in detail to help chemical industry professionals better understand and apply these two sulfur forms.

1. Sulfur Speciation and Classification

Sulfur exists in the form of sulfur (S8) crystals in nature, but it can be converted into various forms in industrial production, including insoluble sulfur, polythiol, polysulfide, etc. Insoluble sulfur generally refers to sulfur in the form of mercaptans, such as polymercaptans (S, n> 2), while sulfur refers to pure polycyclic aromatic sulfur compounds. These two sulfur forms are fundamentally different in structure and function.

2. insoluble sulfur and sulfur chemical properties

  1. The chemical properties of sulfur: sulfur is a kind of polycyclic aromatic sulfur compounds, with strong oxidation of sulfur, prone to disproportionation reaction, the generation of SO and S. In industry, sulfur is mainly used as rubber vulcanization( vulcanization) additives, because of its unique hydrogen sulfide structure.

  2. Chemical properties of insoluble sulfur: Insoluble sulfur is a polythiol in the form of mercaptan, which is different from sulfur in chemical properties. Polythiol has a certain thiol structure, which can enhance its physical and chemical stability through chemical bond interaction. Insoluble sulfur showed inhibitory effect on organic matter in chemical reaction, while sulfur had higher reactivity.

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3. insoluble sulfur and sulfur physical form

  1. The physical form of sulfur: sulfur is a solid substance with small particles and stable physical properties. It is solid or semi-solid at room temperature, but it will decompose into S gas at high temperature.

  2. Physical form of insoluble sulfur: Insoluble sulfur mainly exists in the form of polythiol, with large particles and relatively stable physical properties. Due to the complex structure of the thiol of sulfur, the physical form of insoluble sulfur changes more obviously under different conditions.

4. insoluble sulfur and sulfur applications

  1. Application of sulfur: Sulfur is mainly used in the rubber industry as a vulcanization aid to improve the viscoelastic properties of rubber. Sulfur is also used in matches, sulfur matches and other products.

  2. Application of insoluble sulfur: Insoluble sulfur is mainly used as a raw material for the production of thiols, such as polythiols, which has good solubility and anti-inflammatory effects. Insoluble sulfur is also used for the production of antisolvent, antifriction agent and other industrial products.

5. insoluble sulfur and sulfur production process

  1. Production process of sulfur: The production process of sulfur is mainly synthesized by polycyclic aromatic compounds of sulfur, which is produced by reduction or direct method. The production process of sulfur needs to control the temperature and pressure to ensure the formation of sulfur polycyclic structure.

  2. Production process of insoluble sulfur: The production process of insoluble sulfur is mainly through chemical synthesis to convert elemental sulfur into thiol compounds. The production process involves multiple steps, including the oxidation and reduction of sulfur and the synthesis of polythiols.

6. Insoluble Sulfur and Sulfur: Structural and Functional Differences

  1. Structural differences: The structure of sulfur is polycyclic aromatic sulfur with a stable structure; the structure of insoluble sulfur is polythiol with a more complex structure, including the arrangement of multiple sulfur atoms.

  2. Functional differences: sulfur has strong oxidation, easy to cause chemical reactions; insoluble sulfur has an inhibitory effect on organic matter, stable and not easy to decompose.

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7. environmental aspects of comparison

  1. The environmental protection problem of sulfur: sulfur combustion will produce SO and other harmful gases, causing pollution to the environment, especially in the urban air.

  2. Environmental protection problems of insoluble sulfur: Insoluble sulfur burns relatively clean, does not produce harmful gases such as SO₂, and has better environmental performance.

Although insoluble sulfur and sulfur are similar in morphology, there are significant differences in chemical properties, physical forms, application fields and production processes. When selecting sulfur forms, chemical industry professionals need to consider their chemical properties, application requirements and environmental performance to select the most suitable sulfur form.

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